Preparation,characterization and growth mechanism of ZrO2 nanosheets

High quality single-crystal zirconia nanosheets were successfully prepared via molten salt method, using solvothermally synthesized product as precursor. The effects of heat treatment temperature and soaking time on the phase composition and morphology of samples were investigated by X-ray diffraction, Fourier transform infrared spectroscopy, Thermal analyzer, Raman spectrometer, Field-emission scanning electron microscope and Transmission electron microscope. The results show that zirconia nanosheets with a thickness of 60–80 nm and a width-thickness ratio up to 13 could be obtained by using NaCl and Na₃PO₄ as composite salts at 900 °C for 5 h. The precursors containing Zr–OH and Zr–O bonds have relatively high activity, which is beneficial to crystal growth. In addition, the as-prepared nanosheets with exposed (001) plane are monoclinic-structured and show no distinct defect. The growth behavior of particles during dissolution-recrystallization process is analogous to self-focusing mechanism. The preparation method can be extended to wet-chemical synthesis of other nanomaterials.     

水性环氧硅溶胶复合防腐涂料的制备及其性能

以水性环氧树脂乳液和水性硅溶胶作为成膜基料,添加防锈颜填料,制备了一种有机-无机水性复合防腐涂料。研究了防腐涂料的腐蚀速率以及水性硅溶胶用量对涂层在不同腐蚀介质中的耐蚀性,及其表干时间、实干时间、硬度、附着力和耐盐雾性的影响,通过电化学方法确定了涂层的最佳厚度。结果表明:当防闪锈剂添加量为1%(w)、颜基比为20%(w)、水性硅溶胶的质量占水性环氧树脂质量的15%、漆膜厚度为180μm时,所制复合水性防腐涂料具备良好的耐水、耐碱、耐盐雾性。     

Interaction of two in-line bubbles of equal size rising in viscous liquid

The interaction of bubbles is the key to understand gas–liquid bubbling flow. Two-dimensional axis-symmetry computational fluid dynamics simulations on the interactive bubbles were performed with VOF method,which was validated by experimental work. It is testified that several different bubble interactive behaviors could be acquired under different conditions. Firstly, for large bubbles(d: 4, 6, 8, 10 mm), the trailing bubble rising velocity and aspect ratio have negative correlations with liquid viscosity and surface tension. The influences of viscosity and surface tension on leading bubble are negligible. Secondly, for smaller bubbles(d: 1, 2 mm), the results are complicated. The two bubbles tend to move together due to the attractive force by the wake and the potential repulsive force. Especially for high viscous or high surface tension liquid, the bubble pairs undergo several times acceleration and deceleration. In addition, bubble deformation plays an important role during bubble interaction which cannot be neglected.     

氮氩气流量比对磁控溅射氮化钛薄膜微观结构的影响

采用扫描电镜(SEM)和X射线衍射仪(XRD)研究了氮气流量(5、10、25、50 sccm)及氮氩气流量比(4∶1、3∶2、2∶3、1∶4)对磁控溅射TiN薄膜微观形貌和相组成的影响。结果显示,所得样品具有纳米级TiN薄膜的基本特征。当N2与Ar的总流量为5 sccm,而它们的流量比为4∶1时,可以制得品质较好的蓝紫色TiN薄膜。     

1 200 MPa级冷轧先进高强钢轧制稳定性的分析及控制

针对1 200 MPa级冷轧先进高强钢轧制不稳定问题,对热轧原料组织性能均匀性、冷轧压缩比、冷连轧机组轧制策略等进行了分析。结果表明,热轧工序投入边部加热器,采用分段冷却等手段,可有效降低热轧原料头尾部组织性能差异,保证通卷性能均匀,进而保证通卷轧制过程稳定;通过优化冷连轧机组压缩比,可有效降低材料本身的加工硬化强度,进而避免连轧机组后面机架的轧制超负荷情况;通过优化冷连轧机组轧制策略,可保证轧制过程中各机架均匀变形,避免出现轧制力差异较大的情况,进而保证轧制过程稳定。采用上述措施,1 200 MPa级冷轧先进高强钢轧制力控制在约15 000 kN,厚度精度控制在±0.06 mm以内,可保证该级别高强钢的稳定轧制。     

桩土复合路基静载试验改进方法研究

静载试验作为复合路基的一种重要检测手段而广泛应用,然而,在工程质量检测中,常出现检测结果与实际情况不符的情况,除人为操作因素外,垫层模拟过于简单是主要原因。借助引入弹性垫层,提出一种桩土复合路基静载试验改进方法。首先,基于数值模拟计算,建立复合路基桩土应力比n和桩土相对位移Δs、弹性垫层厚度h和弹性垫层模量E的函数关系;其次,通过模拟结果和路堤荷载结果对比,确定不同桩型复合路基静载试验中弹性垫层参数选择范围,最后,利用现场对比试验和实测结果,论证桩土复合路基静载试验改进方法的正确性和可靠性。     

煤与天然气气流床共气化制合成气试验研究

为提高煤、天然气资源综合利用效率,优化合成气成分,进行了煤与天然气气流床共气化技术研究。介绍了煤与天然气气流床共气化的试验装置及工艺流程,考察了气化温度、压力、水煤浆浓度、CH4与煤比对共气化反应的影响。结果表明,气化温度和CH4与煤比是共气化反应的主要影响因素,较高的气化温度对共气化反应有利,气化温度为1 350℃时,共气化指标较好,有效气体积分数大于90%;随着CH4与煤比的增大,合成气n(H2)/n(CO)增高。CH4与煤比为0.9 m3/kg时,合成气中n(H2)/n(CO)约1.2。根据后续合成工艺要求,通过调节气化温度和CH4与煤比,可获得n(H2)/n(CO)在0.8~2.0的合成气。     

部分传输序列的遗传模拟退火搜索方法

在正交频分复用(OFDM)系统中,基于遗传算法的部分传输序列(GA-PTS)技术有效地降低了 PTS 的计算复杂度,但在 改进峰值-平均功率比(PAPR)性能方面却并不理想。 为此,提出在遗传算法中嵌入模拟退火(SA)算子从而构造一种混合的遗 传模拟退火(GSA)算法,并把它应用于对 PTS 的最优相位因子进行搜索。 首先,通过对 PTS 相位因子编码形成染色体,采用随 机元素组成的染色体作为遗传算法的初始群体,并评估每个染色体的适应度值。 然后,根据适应度值选择染色体,建立染色体 的变异规则和交叉规则,对群体进行迭代进化。 最后,群体中的染色体利用退火温度进行更新,从而产生出新的下一代种群。 仿真结果说明,与 GA-PTS 方案相比,该方法不仅能降低计算负担,而且能够有效地降低 OFDM 系统 PAPR 值。     

A modified two-dimensional numerical method for prediction of outer wall temperature distribution of rectangular micro-combustors

Two-dimensional (2D) numerical models are frequently adopted to investigate combustion and thermal performances in rectangular micro-channels for micro-thermophotovoltaic and thermoelectric devices. However, large error may exist by applying a simple 2D model. In the present work, the outer wall temperature distributions predicted by 3D model and simple 2D model were compared. The results showed that the maximum relative error of the simple 2D model depends significantly on the aspect ratio (α) of the micro-channel. To be specific, the maximum relative error was >30% for α = 1 and > 10% for 2≤α ≤ 4. However, it was <5% for α ≥ 9. A new 2D model was proposed to modify the underestimated heat loss ratio. The new computational results demonstrated that the maximum relative error of α = 1 decreased to 8.07% and for micro-channels with α ≥ 2, all the maximum relative errors are <5%. In summary, the modified 2D numerical model can achieve a satisfactory prediction with low computation cost.     

Improvement of biohythane production from Chlorella sp. TISTR 8411 biomass by co-digestion with organic wastes in a two-stage fermentation

The suitability of molasses, Napier grass (Pennisetum purpureum), empty fruit bunches (EFB), palm oil mill effluent (POME), and glycerol waste as a co-substrate with Chlorella sp. TISTR 8411 biomass for biohythane production was investigated. Mono-digestion of Chlorella biomass had hydrogen and methane yield of 23–35 and 164–177 mL gVS⁻¹, respectively. Co-digestion of Chlorella biomass with 2–6% TS of organic wastes was optimized for biohythane production with hydrogen and methane yield of 17–75 and 214–577 mL gVS⁻¹, respectively. The hydrogen and methane yield from co-digestion of Chlorella biomass with molasses, POME, and glycerol waste was increased by 8–100% and 80–264%, respectively. The biohythane production of co-digestion of Chlorella was 6–11 L L-mixed waste⁻¹ with an optimal C/N ratio range of 19–41 and H₂/CH₄ ratio range of 0.06–0.3. Co-digestion of Chlorella biomass was significantly improved biohythane production in term of yield, production rate, and kinetics.